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Answer :

Como

Explanation:

"Como" in that sentence is asking, "How is the new girl?" "Ella is muy simpatica" is used to describe the girl as nice in response to the question.

"Quien" would be asking, "Who is the new girl?" "Ella is muy simpatica" doesn't relate to that question.

Answer:

¿Como

Explanation:

¿Cómo es la chica nueva?